期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 4, 页码 2478-2485出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cy00073d
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资金
- National Natural Science Foundation of China [21407088, 21221004]
- National High-Tech Research and the Development (863) Program of China [2013AA065401, 2013AA065304]
- International Postdoctoral Exchange Fellowship Program of China [20130032]
- Brook Byers Institute
The idea of rational design of perovskite catalysts for NOx storage and reduction (NSR) starts from DFT studies on Sr-doped LaMnO3 (001) plane models: a Mn-terminated plane (Mn-ter) has a higher activity than La- or Sr-ter planes; the number of A-site defects increases when Sr is doped on the surface; O-vacancy formation energies for both La- and Mn-ter gradually decrease with increased Sr loading, and the values for La-ter are always larger than for Mn-ter with the same Sr loading, indicating that the O-vacancy formation is facile on Mn-ter with Sr-doping. This model yields the highest reactivity for oxidation and the lowest energy barrier for O-vacancy formation. A surface tuning method for La0.5Sr0.5MnO3 is introduced. With the exception of the promotion of surface area and pore volume, the ratio of Sr/La and the number of surface-active oxygen atoms and Mn4+ cations exposed on the outermost layers are improved with an increased contact time between the raw materials and dilute HNO3. However, overtreatment leads to a less stable phase of MnO2 with a high reducibility but significantly restrained NOx adsorption. NSR performances under lean-burn/fuel-rich cycles are measured, and the results correspond well with the NO adsorption or oxidation behaviors and DFT calculations.
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