期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 5, 期 1, 页码 562-571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cy01064g
关键词
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资金
- National Natural Science Foundation [21373160]
- Scientific Research Program Foundation of Shaanxi Provincial Education Department [2013JK0701]
- Scientific Research Culture Foundation of Xi'an University of Science and Technology [201117]
A ring-opening copolymerization of styrene oxide with maleic anhydride was performed by applying a series of asymmetrical bis-Schiff-base metal(III) catalysts. The chromium catalyst exhibited the best performance and therefore the catalyst (salen)CrCl (salen = 4-((Z)-(2-((E)-3,5-dibromo-2-hydroxybenzylideneamino) phenylimino)(phenyl) methyl)-1-(4-chlorophenyl)-3-methyl-1H-pyrazol-5(4H)-one) (7) was chosen for further studies. The investigations on the effect of different co-catalysts on the copolymerization of styrene oxide and maleic anhydride revealed that DMAP showed the highest activity, followed by PPN+Cl-, whereas Ph3P showed the lowest activity. H-1 NMR and MALDI-TOF-MS spectra of the copolymers formed confirmed the alternating microstructures. The copolymerization of styrene oxide with maleic anhydride bearing a double bond in its structure was shown to be highly dependent on the polymerization condition, type of co-catalyst, monomer to catalyst ratio, temperature and time used in the copolymerization reaction. Applying chain transfer agents, alcohols, resulted in a decrease in molecular weight.
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