期刊
PURE AND APPLIED CHEMISTRY
卷 86, 期 2, 页码 181-189出版社
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2014-5024
关键词
hydration; hypermobile water; nucleotides; phosphate; protein properties; rotational entropy; spectroscopy
资金
- [20118001]
- [20118002]
- [20118003]
- [20118004]
- [20118005]
- [20118006]
- [20118007]
- [20118009]
- [20118008]
- Grants-in-Aid for Scientific Research [23310071, 20118001] Funding Source: KAKEN
Experimental observation by high-resolution microwave dielectric spectroscopy of hydration properties of alkali halide ions, adenosine phosphate ions, and F-actin revealed the existence of hypermobile water (HMW) molecules around those solutes. To understand the molecular process of HMW, two theoretical approaches are reviewed here. One is based on a statistical mechanical approach to analyze the rotational freedom of water molecules around a charged particle. Another approach reports direct calculation of dielectric relaxation process of water molecules around an ion. Experimentally observed HMW molecules are theoretically explained with the significance of multi-correlations among an ion and water molecules.
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