期刊
PURE AND APPLIED CHEMISTRY
卷 85, 期 2, 页码 397-404出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-12-08-11
关键词
coordination complexes; halogen bonding; self-assembly; supramolecular chemistry; X-ray single-crystal diffraction
资金
- National Plan for Science and Technology NPST-KSU grant [ENE 09-909-02]
With the current advances in our understanding of molecular components in the solid-state world, the relation between energy and geometry remains controversial. In this study, we deliver a concise account for supramolecular chemistry, and in order to illustrate some of its concepts we describe some structural and theoretical analyses for two unique cases of our work. We elaborate on a supramolecular model of controlled one-pot host-guest metal-mediated self-assembly reaction inside iron coordination polymer grid architecture, and we review halogen bonding by specifically observing M-Cl center dot center dot center dot Cl-M intermolecular interactions using Cambridge Structural Database (CSD) hit analyses with theoretical calculations.
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