期刊
PURE AND APPLIED CHEMISTRY
卷 85, 期 4, 页码 755-761出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-12-10-23
关键词
alkenes; bromine; catalysis; diamination; oxidation
资金
- Spanish Ministry of Economy [CTQ2011-25027]
- ICIQ Foundation
- Fonds der Chemischen Industrie
- ICREA Funding Source: Custom
The development of an intramolecular vicinal diamination protocol using metal-free conditions is discussed. The reaction uses a bromide source to generate a Br(I) catalyst in situ from a benign terminal oxidant such as sodium chlorite. The reaction is of great scope and surpasses the transition-metal catalyses developed so far for these types of reactions.
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