期刊
PURE AND APPLIED CHEMISTRY
卷 83, 期 3, 页码 633-644出版社
INT UNION PURE APPLIED CHEMISTRY
DOI: 10.1351/PAC-CON-10-08-06
关键词
asymmetric catalysis; C,P-complexation cross-coupling; green chemistry; phosphorus ligands
Transition-metal (TM) complexes of new phosphines, readily prepared by a straight forward three-step modular synthesis, were successfully employed in difficult cross-coupling reactions conducted under mild conditions (water, open-flask, low temperature) that aspire to meet green chemistry criteria. High yielding catalyzed by bismuth or rhodium complexes oxidative arylation of naphthoquinone gave the key 2-arylnaphthoquinone intermediates for facile bismuth triflate-catalyzed Michael addition of secondary phosphine oxides. Subsequent O-methylation and reductions of the resulting products gave access to the target air-stable phosphine ligands in good overall yields (up to 60 %).
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