期刊
PURE AND APPLIED CHEMISTRY
卷 83, 期 7, 页码 1391-1406出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/PAC-CON-10-12-03
关键词
1-alkenes; chemometrics; ionic liquids; linear terminal olefins; 1-olefins; oligomerisation
资金
- EPSRC [EP/D029538/1]
- BP, QUILL
- Engineering and Physical Sciences Research Council [EP/D029538/1] Funding Source: researchfish
A Lewis acidic chlorogallate(III) ionic liquid, 1-ethyl-3-methylimidazolium hepta-chlorodigallate(III), [C(2)mim][Ga2Cl7], was successfully used to oligomerise 1-pentene. The influence of temperature, time, catalyst concentration, and stirring rate on conversion and product distribution was modelled using a design of experiment (DoE) approach (chemometrics). The process was optimised for lubricant base oils production; the C20-C50 fraction (where Cn indicates the number of carbons in the oligomer) was maximised, while the heavier oligomer fraction (>C50) was minimised.
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