期刊
PURE AND APPLIED CHEMISTRY
卷 80, 期 5, 页码 993-1003出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880050993
关键词
organosulfur; transition metals; catalysis; addition; C-H substitution; metathesis
Rhodium complexes are efficient catalysts for the synthesis of organosulfur compounds. They catalyze the addition reaction of organosulfur groups to unsaturated compounds, the substitution of C-H with organosulfur groups, and single-bond metathesis reactions. They cleave S-S bonds and transfer the organosulfur groups to various organic and inorganic molecules, including alkynes, allenes, disulfides, sulfur, isonitriles, imines, diphosphines, thiophosphinites, hydrogen, 1-alkylthio-1-alkynes, thioesters, and allyl sulfides.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据