期刊
PURE AND APPLIED CHEMISTRY
卷 80, 期 5, 页码 1187-1194出版社
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200880051187
关键词
boron; lithium; boryl complex; boryl anion; crystal structure
The first boryl anion, boryllithium, was synthesized by a reduction of bromoborane precursor using lithium naphthalenide in tetrahydrofuran (THF) solvent at -45 degrees C. Structural and spectroscopic study revealed an ionic character of B-Li bond. Boryllithium could be utilized as a Source of boryl ligand in the transition-metal chemistry. Structural and spectroscopic features of the resulting boryl complexes confirmed the large trans influence of boryl ligand.
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