Removal of toxic chromium from aqueous solution, wastewater and saline water by marine red alga Pterocladia capillacea and its activated carbon

Pterocladia capillacea, a red marine macroalgae, was tested for its ability to remove toxic hexavalent chromium from aqueous solution. A new activated carbon obtained from P. capillacea via acid dehydration was also investigated as an adsorbent for toxic chromium. The experiments were conducted to study the effect of important parameters such as pH, chromium concentration and adsorbent weight. Batch equilibrium tests at different pH conditions showed that at pH 1.0, a maximum chromium uptake was observed for both inactivated dried red alga P. capillacea and its activated carbon. The maximum sorption capacities for dried red alga and its activated carbon were about 12 and 66 mg g(-1), respectively, as calculated by Langmuir model. The ability of inactivated red alga P. capillacea and developed activated carbon to remove chromium from synthetic sea water, natural sea water and wastewater was investigated as well. Different isotherm models were used to analyze the experimental data and the models parameters were evaluated. This study showed that the activated carbon developed from red alga P. capillacea is a promising activated carbon for removal of toxic chromium. (C) 2011 Production and hosting by Elsevier B.V. on behalf of King Saud University.