期刊
ADVANCED ENERGY MATERIALS
卷 5, 期 21, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201500877
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资金
- Office of Science, Office of Basic Energy Sciences, U.S. Department of Energy [DE-AC02-05CH11231]
- National Science Foundation Graduate Research Fellowship Program [DGE-1144085]
- Office of Naval Research [N00014-14-1-0101]
- U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences, Materials Science and Engineering Division [DE-FG02-98ER45737]
Whereas the role of molecularly mixed domains in organic photovoltaic devices for charge generation is extensively discussed in the literature, the impact on charge recombination and thus fill factor is largely unexplored. Here, a combination of soft X-ray techniques enables the quantification of phases at multiple length scales to reveal their role regarding charge recombination in a highly efficient solution processed small molecule system 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl) bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole) (p-DTS(FBTTh2)(2)). A quantitative (linear) relationship between the average composition variations and the device fill-factor is observed. The results establish the complex interrelationship between average phase purity, domain size, and structural order and highlight the requirement of achieving sufficient phase purities to diminish bimolecular and geminate recombination in solution processed small molecule solar cells.
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