期刊
ADVANCED ENERGY MATERIALS
卷 5, 期 22, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201501156
关键词
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类别
资金
- NSFC [51222210, 11234013, Y5JC011E21]
- 973 Projects [2012CB932900]
- One Hundred Talent Project of Chinese Academy of Sciences
Sodium-ion batteries are promising for grid-scale storage applications due to the natural abundance and low cost of sodium. However, few electrodes that can meet the requirements for practical applications are available today due to the limited routes to exploring new materials. Here, a new strategy is proposed through partially/fully substituting the redox couple of existing negative electrodes in their reduced forms to design the corresponding new positive electrode materials. The power of this strategy is demonstrated through the successful design of new tunnel-type positive electrode materials of Na-0.61[Mn0.61-xFexTi0.39]O-2, composed of non-toxic and abundant elements: Na, Mn, Fe, Ti. In particular, the designed air-stable Na-0.61[Mn0.27Fe0.34Ti0.39]O-2 shows a usable capacity of approximate to 90 mAh g(-1), registering the highest value among the tunnel-type oxides, and a high storage voltage of 3.56 V, corresponding to the Fe3+/Fe4+ redox couple realized for the first time in non-layered oxides, which was confirmed by X-ray absorption spectroscopy and Mossbauer spectroscopy. This new strategy would open an exciting route to explore electrode materials for rechargeable batteries.
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