期刊
ACS COMBINATORIAL SCIENCE
卷 17, 期 5, 页码 253-302出版社
AMER CHEMICAL SOC
DOI: 10.1021/co500146u
关键词
diversity-oriented synthesis; dienes; Diels-Alder reaction; green chemistry; polycyclics; amino acids
资金
- DST
- CSIR New Delhi
- UGC, New Delhi
We describe diverse approaches to various dienes and their utilization in the Diels-Alder reaction to produce a variety of polycycles. The dienes covered here are prepared by simple alkylation reaction or via the Claisen rearrangement or by enyne metathesis of alkyne or enyne building blocks. Here, we have also included the Diels-Alder chemistry of dendralenes, a higher analog of cross-conjugated dienes. The present article is inclusive of o-xylylene derivatives that are generated in situ starting with benzosultine or benzosulfone derivatives. The Diels-Alder reaction of these dienes with various dienophiles gave diverse polycyclic systems and biologically important targets.
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