期刊
ACS COMBINATORIAL SCIENCE
卷 17, 期 11, 页码 691-697出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscombsci.5b00109
关键词
beta-phosphonomalonate; multicomponent reaction; organocatalyst; solvent-free
资金
- Fusion Research Program for Green Technologies through the National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [2012M3C1A1054502]
- BK21 PLUS Program
An efficient, one-pot, di-n-butylamine-catalyzed, three-component synthesis of beta-phosphonomalonates has been developed. A wide range of substrates, including aromatic and fused aromatic aldehydes, were condensed with enolizable C-H activated compounds and dialkylphosphites to give the desired products in excellent yields. This method provides an eco-friendly alternative approach to rapid construction of a diversity-oriented library of beta-phosphonomalonates.
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