期刊
ACS CATALYSIS
卷 5, 期 8, 页码 4713-4724出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00820
关键词
diiminopyridine; transition metal complex; catalysis; olefin polymerization; aluminum alkyl; redox reaction; cooperative effects
资金
- National Natural Science Foundation of China (NSFC) [U1362204, 21374123]
- Chinese Academy of Sciences
Diiminopyridyl metal complexes, first characterized several decades ago, found practical application in 1998 when they were used as precatalysts in coordinative ethylene polymerization. This discovery contributed to the so-called postmetallocene revolution and triggered the large-scale experimental and theoretical research aimed at understanding diversified diiminopyridine chemistry. The results of this quest, some of which were intriguing and difficult to anticipate, are discussed and summarized in the current Review.
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