期刊
ACS CATALYSIS
卷 5, 期 12, 页码 7446-7479出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02070
关键词
stereoselective catalysis; [2,3]-rearrangement; allylic oxonium ylides; allylic ammonium ylides; allylic sulfonium ylides; O-propargylic oximes; allylic sulfoxides; allylic N-oxides
资金
- Royal Society
- European Research Council under the European Union [279850]
- European Union [PITH-GA-2013-607044]
[2,3]-Sigmatropic rearrangement processes of allylic ylides or their equivalents can be applied to a variety of different substrates and generate products of wide interest/applicability to organic synthesis. This review describes the development and applications of stereoselective [2,3]-rearrangement reactions in which a substoichiometric amount of a catalyst is used in either the formation of the reactive intermediate or the [2,3]-rearrangement step itself.
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