期刊
ACS CATALYSIS
卷 5, 期 11, 页码 7004-7007出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b01972
关键词
lignin; lignin models; tandem catalysis; ether hydrogenolysis; ester hydrogenolysis; biomass
资金
- U.S. Department of Energy [DE-AC0206CH11357]
- NSF grant [CHE-1213235]
- Institute of Atom-efficient Chemical Transformation (IACT), an Energy Frontier Research Center - U.S. Department of Energy, Office of Sciences, and Office of Basic Energy Sciences
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1464488] Funding Source: National Science Foundation
Selective ether/ester C-O bond hydrogenolysis of an acetylated lignin model is achieved using a thermodynamically leveraged tandem catalytic strategy. Acetylation serves to (1) solubilize both lignin and lignin models and to (2) modify the reactivity of pendant hydroxy groups to promote more selective C-O cleavage.
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