期刊
ACS CATALYSIS
卷 6, 期 1, 页码 447-450出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02022
关键词
fluorination; hypervalent iodines; iodofluorination; palladium catalysis; alkenes; difunctionalization
资金
- Swedish Research Council
- Knut och Alice Wallenbergs Foundation
The application of an air- and moisture-stable fluoroiodane reagent was investigated in the palladium-catalyzed iodofluorination reaction of alkenes. Both the iodo and fluoro substituents arise from the fluoroiodane reagent. In the case of certain palladium catalysts, the alkene substrates undergo allylic rearrangement prior to the iodofluorination process. The reaction is faster for electron-rich alkenes than for electron-deficient ones.
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