期刊
ACS CATALYSIS
卷 6, 期 1, 页码 230-234出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02218
关键词
ruthenium catalysis; C-H bond activation; alkenylation; hydrogen evolution; oxidant free; ambient temperature
资金
- INSA, India [SP/YSP/99/2014]
- CSIR
A ruthenium-catalyzed oxidant-free highly regioselective ortho alkenylation of substituted aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the presence of AgSbF6 and acetic acid in ClCH2CH2Cl at room temperature is described. The alkenylation reaction provides ortho alkenylated aromatics along with evolution of H-2 gas. In the reaction, no oxidant was used, and the whole catalytic reaction has occurred without changing the oxidation state of the metal.
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