期刊
ACS CATALYSIS
卷 5, 期 8, 页码 4734-4742出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00909
关键词
triarylmethane; transition metal catalysis; arylation; enantioselectivity; enantiospecificity
资金
- KAKENHI from JSPS [26810056]
- Hattori Hokokai Foundation
- JSPS
- NU
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Foundation for Innovation (CFI)
- Grants-in-Aid for Scientific Research [26810056, 26288023] Funding Source: KAKEN
Triarylmethanes and related compounds are fascinating molecules because of their structural and physical properties, many potential applications in organic functional materials, and high biological activity. Recently, catalysis has provided new synthesis routes to triarylmethanes with high selectivity and diversity, including the possibility of preparing enantiomerically enriched derivatives, which is typically challenging using classical methods. This Perspective reviews recent advances in new synthesis approaches to triarylmethanes using well-defined catalysts. These methods will allow the development of new, unexplored triarylmethane structures.
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