期刊
ACS CATALYSIS
卷 5, 期 2, 页码 909-919出版社
AMER CHEMICAL SOC
DOI: 10.1021/cs5018369
关键词
Pt/H-ZSMS; soot oxidation; surface oxygenated complexes; surface acid sites; NO2 preferential adsorption
资金
- Ministry of Science and Technology of China [2013AA061902]
- Ministry of Education of China [113007A]
- Key Laboratory of Advanced Materials of Ministry of Education
Pt/H-ZSMS and Pt/Al2O3 with similar surface Pt particle sizes and chemical states were prepared by incipient wetness impregnation as catalysts for soot oxidation. Pt/H-ZSMS exhibits obviously higher activities in both O-2 and NO + O-2 than Pt/Al2O3. On the basis of the results obtained with in situ DRIFT and other structural and surface property characterizations, the high catalytic activity of Pt/H-ZSMS is currently attributed to two main factors. First, the acidic H-ZSMS support inhibits NO2 adsorption on the catalyst, leading to a preferential adsorption of NO2 on the surface of soot and providing more chances for NO2-soot reactions. Second, the strong acid sites on the surface of Pt/H-ZSMS can participate in the catalytic formation and decomposition of surface oxygenated complexes. Consequently, a high achieved on the Pt/H-ZSMS catalyst.
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