期刊
ACS CATALYSIS
卷 5, 期 7, 页码 4268-4275出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00692
关键词
CON-type zeolite; aluminosilicate; direct synthesis; postsynthesis; MTO reaction; Al distribution in the framework
资金
- Japan Technological Research Association of Artificial Photosynthetic Chemical Process (ARPChem)
The CON-type aluminosilicate zeolites, which consist of a three-dimensional pore system with 12-, 12-, and 10-membered ring pores have been prepared by postsynthesis and the newly developed direct-synthesis methods. We first found that the CON-type aluminosilicate zeolites exhibited a higher catalytic performance in the methanol to olefins (MTO) reaction in terms of duration and propene selectivity than the MFI and *BEA-type aluminosilicate zeolites. They exhibited high propene selectivity, low ethene selectivity, and a very long catalytic life compared to Beta and ZSM-5; the selectivity for C3-C4 olefins reached 80%. Interestingly, the CON-type aluminosilicate zeolite synthesized by the direct-synthesis method showed a much longer catalytic lifetime than the one obtained by the postsynthesis method. The Al-27 MAS and Al-27 MQMAS NMR spectra suggest that there is a significant difference in the state of tetrahedrally coordinated Al species between the directly and postsynthesized zeolites, leading to the marked difference in the catalytic performance.
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