期刊
ACS CATALYSIS
卷 5, 期 6, 页码 3504-3513出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b00086
关键词
ceria; gold; surfaces; catalysis; transmission electron microscopy
资金
- MINECO/FEDER [MAT2013-40823R, CSD09-00013]
- European Union [312483-ESTEEM2]
- Spanish Ministry of Education
A partial transformation of the (100} surfaces of ceria nanocubes into a set of nanometer-heighted, {111}-ounded, peaks was achieved by an oxidation treatment at 600 degrees C. This particular type of surface nanostructuration allows the preparation of CeO2 nanoparticles in which {111) nanofacets contribute significantly to their surface crystallography. This transformation of the surface structure plays a key influence on the behavior of ceria as a support of gold catalysts. Thus, the appearance of well-developed {111}-nanofacets leads to a much higher efficiency in the usage of this noble metal in the synthesis of catalysts when prepared by the deposition precipitation method. Moreover, gold catalysts supported on the surface-reconstructed oxide present an intrinsic (per gold surface atom) CO oxidation activity much higher than that of catalysts prepared on the nontreated oxide.
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