期刊
PROGRESS IN ORGANIC COATINGS
卷 75, 期 3, 页码 224-230出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2012.05.003
关键词
Exopolysaccharides; Anti-corrosion; Coatings; Waterborne polymers; Sustainability
资金
- Dutch governmental Economy Ecology Technology (E.E.T.) program [EETK01129]
Exopolysaccharides (EPS) are a class of renewable polymers that show interesting anti-corrosive properties and could potentially be used as an alternative for zinc phosphates. When combined with a waterborne styrene-acrylic polymer dispersion (SA-1), exopolysaccharides were shown to give an improvement in the anti-corrosive performance. Electrochemical studies show higher charge transfer resistance (R-ct) values for the SA-1/EPS combinations as compared to the SA-1 itself suggesting that in the presence of EPS less corrosion took place. Outdoor exposure test shows that the presence of EPS188 gave good corrosion protection for up to a year when exposed under marine conditions. The distribution of EPS modification throughout the coating was made visible using Confocal Laser Scanning Microscopy and indicated that EPS was distributed rather homogeneously. A working mechanism was proposed in which the carboxylic acid groups on the oxidised EPS form a complex with iron ions formed by the anodic reaction and this insoluble complex forms a protective layer between the coating and metal. The results in this paper show that by using renewable polysaccharide additives the anti-corrosive coating performance can be improved. (C) 2012 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据