期刊
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL
卷 22, 期 4, 页码 341-346出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.pnsc.2012.06.005
关键词
Regenerated cellulose; Graphene oxide; Layer-by-layer assembly; Multilayer films
资金
- Fund of National Natural Science [51103019, 21174027]
A key challenge in the preparation of nanoplatelet-filled polymer composites is the ability to realize the nanometer-level dispersion and the planar orientation of nanosheets in polymer matrices. In this report, multilayerfilms were successfully fabricated by layer-by-layerassembly of regeneratedcellulose and grapheneoxide, in which grapheneoxide nanosheets were used as the building blocks. The thickness of 50 layerfilm is about 20 mu m and it exhibits a high degree of smoothness. This may be attributed to the well-defined layered structure with high degree of planar orientation and nanolevel assemblies of grapheneoxide nanosheets in the polymer matrices. Typical field emission scanning electron microscope images demonstrate an ordered arrangement of layers. The electrical conductivity of the multilayerfilms shows a remarkable increase with increasing layer of the films. A significant enhancement of mechanical properties has been achieved, that is, a 110.8% improvement of elastic modulus and a 262.5% increase of hardness respectively. (C) 2012 Chinese Materials Research Society. Production and hosting by Elsevier Ltd. All rights reserved.
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