期刊
PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
卷 468, 期 2143, 页码 2017-2034出版社
ROYAL SOC
DOI: 10.1098/rspa.2012.0072
关键词
allylic oxidation; cyclohexane; carboxylation; metal-organic frameworks; MIL-101; single-site heterogeneous catalysts
资金
- Russian Foundation for Basic Research [09-03-12112, 09-03-93109]
In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal-organic frameworks of the MIL-101 family (Fe-and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants-O-2 and tert-butyl hydroperoxide-and (ii) coupling reaction of organic oxides with CO2. A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst's resistance to metal leaching and the nature of catalysis.
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