4.5 Article

Boundary-induced electrophoresis of uncharged conducting particles: remote wall approximations

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ROYAL SOC
DOI: 10.1098/rspa.2008.0322

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electrokinetics; asymptotic methods; Stokes flow

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An initially uncharged ideally polarizable particle is freely suspended in an electrolyte solution in the vicinity of an uncharged dielectric wall. A uniform electric field is externally applied parallel to the wall, inflicting particle drift perpendicular to it. Assuming a thin Debye thickness, the electrokinetic flow is analysed for large particle wall separations using reflection methods, thereby yielding an asymptotic approximation for the particle velocity. The leading-order correction term in that approximations stems from wall polarization.

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