期刊
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
卷 110, 期 22, 页码 8801-8806出版社
NATL ACAD SCIENCES
DOI: 10.1073/pnas.1306623110
关键词
nanomaterials; thermochemistry
资金
- US Department of Energy [DE-FG02-97ER14749]
- Institute for Advanced Studies in Basic Sciences
- National Elite Foundation
- National Science Foundation [EAR-1231322]
- U.S. Department of Energy (DOE) [DE-FG02-97ER14749] Funding Source: U.S. Department of Energy (DOE)
Previous measurements show that calcium manganese oxide nanoparticles are better water oxidation catalysts than binary manganese oxides (Mn3O4, Mn2O3, and MnO2). The probable reasons for such enhancement involve a combination of factors: The calcium manganese oxide materials have a layered structure with considerable thermodynamic stability and a high surface area, their low surface energy suggests relatively loose binding of H2O on the internal and external surfaces, and they possess mixed-valent manganese with internal oxidation enthalpy independent of the Mn3+/Mn4+ ratio and much smaller in magnitude than the Mn2O3-MnO2 couple. These factors enhance catalytic ability by providing easy access for solutes and water to active sites and facile electron transfer between manganese in different oxidation states.
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