期刊
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
卷 109, 期 39, 页码 15606-15611出版社
NATL ACAD SCIENCES
DOI: 10.1073/pnas.1203122109
关键词
artificial photosynthesis; polypyridyl Ru complexes; proton coupled electron transfer; single-site catalysis; solar fuels
资金
- University of North Carolina Energy Frontier Research Center (EFRC): Center for Solar Fuels an EFRC
- Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (BES) [DE-SC0001011]
- DOE BES EFRC Award [DE-SC0001011]
- Army Research Office [W911NF-09-1-0426]
The metal complex [(tpy)(Mebim-py)Ru-II(S)](2+) (tpy = 2,2' : 6'0,2 ''-terpyridine; Mebim-py = 3-methyl-1-pyridylbenzimidazol-2-ylidene; S = solvent) is a robust, reactive electrocatalyst toward both water oxidation to oxygen and carbon dioxide reduction to carbon monoxide. Here we describe its use as a single electrocatalyst for CO2 splitting, CO2 -> CO + 1/2O(2), in a two-compartment electrochemical cell.
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