期刊
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
卷 109, 期 5, 页码 1413-1418出版社
NATL ACAD SCIENCES
DOI: 10.1073/pnas.1116289109
关键词
ballistic energy transport; PEG oligomers; relaxation-assisted 2DIR
资金
- National Science Foundation [CHE-0750415]
- Air Force Office of Scientific Research [FA9550-10-1-0007]
- IBM Corporation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0750415] Funding Source: National Science Foundation
A series of azido-PEG-succinimide ester oligomers with a number of repeating PEG units of 0, 4, 8, and 12 (azPEG0, 4, 8, and 12) was investigated using a relaxation-assisted two-dimensional infrared (RA 2DIR) spectroscopy method. The RA 2DIR method relies on the energy transport in molecules and is capable of correlating the frequencies of vibrational modes separated by large through-bond distances. Excitation of the azido group in the compounds at ca. 2,100 cm(-1) generates an excess energy which propagates in the molecule as well as dissipates into the solvent. We discovered that a part of the excess energy propagates ballistically via the covalent backbone of the molecules with a constant speed of ca. 550 m/s. The transport is described as a propagation of a vibrational wave-packet having a mean-free-path length of 10-15 angstrom. The discovery has the potential for developing new efficient signal transduction strategies for molecular electronics and biochemistry. It also permits extending the distances accessible in RA 2DIR structural measurements up to ca. 60 angstrom.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据