期刊
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
卷 106, 期 26, 页码 10471-10476出版社
NATL ACAD SCIENCES
DOI: 10.1073/pnas.0810145106
关键词
kinetics; slippage; supramolecular chemistry; thermodynamics
资金
- National Research School Combination Catalysis Controlled
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek
- Vidi and Vici
- Koninklijke Nederlandse Akademie van Wetenschappen
- Nanoned
The cooperative binding effects of viologens and pyridines to a synthetic bivalent porphyrin receptor are used as a model system to study how the magnitudes of these effects relate to the experimentally obtained values. The full thermodynamic and kinetic circles concerning both activation and inhibition of the cage of the receptor for the binding of viologens were measured and evaluated. The results strongly emphasize the apparent character of measured binding and rate constants, in which the fractional saturation of receptors with other guests is linearly expressed in these constants. The presented method can be used as a simple tool to better analyze and comprehend the experimentally observed kinetics and thermodynamics of natural and artificial cooperative systems.
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