Direct blast initiation of spherical gaseous detonations in highly argon diluted mixtures

In this study, direct initiation of spherical detonations in highly argon diluted mixtures is investigated. Direct initiation is achieved via a high voltage capacitor spark discharge and the critical energy is estimated from the analysis of the current output. Stoichiometric acetylene-oxygen mixtures highly diluted with 70% argon is used in the experiment. Previous investigations have suggested that detonations in mixtures that are highly diluted with argon have been shown to be stable in that the reaction zone is at least piecewise laminar described by the ZND model and cellular instabilities play a minor role on the detonation propagation. For the acetylene-oxygen mixture that is highly diluted with argon, the experimental results show that the critical energy where the detonation is stable is in good agreement with the Zel'dovich criterion of the cubic dependence on the ZND reaction length, which can be readily determined using the chemical kinetic data of the reaction. The experimental results are also compared with those estimated using Lee's surface energy model where empirical data on detonation cell sizes are required. Good agreement is found between the experimental measurement and theoretical model prediction, where the breakdown of the 13 lambda relationship for critical tube diameter - and hence a different propagation and initiation mechanism - is elucidated in highly argon diluted mixtures and this appears to indicate that cellular instabilities do not have a prominent effect on the initiation process of a stable detonation. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.