期刊
PROCEEDINGS OF THE COMBUSTION INSTITUTE
卷 33, 期 -, 页码 995-1002出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.proci.2010.05.084
关键词
Stagnation-flow ignition; Laminar flame speeds; Mechanism reduction; Butanol; Methyl butanoate
资金
- Carbon Mitigation Initiative (CMI)
- BP Corp.
- Princeton University
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001198]
The non-premixed ignition temperature of n-butanol (CH3CH2CH2CH2OH), iso-butanol ((CH3)(2) CHCH2OH) and methyl butanoate (CH3CH2CH2COOCH3) was measured in a liquid pool assembly by heated oxidizer in a stagnation flow for system pressures of 1 and 3 atm. In addition, the stretch-corrected laminar flame speeds of mixtures of air-n-butanol/iso-butanol/methyl butanoate were determined from the outwardly propagating spherical flame at initial pressures of up to 2 atm, for an extensive range of equivalence ratio. The ignition temperature and laminar flame speeds of n-butanol and methyl butanoate were computationally simulated with three recently developed kinetic mechanisms in the literature. Dominant reaction pathways to ignition and flame propagation were identified and discussed through a chemical explosive mode analysis (CEMA) and sensitivity analysis. The detailed models were further reduced through a series of systematic strategies. The reduced mechanisms provided excellent agreement in both homogeneous and diffusive combustion environments and greatly improved the computation efficiency. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.
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