期刊
POWDER TECHNOLOGY
卷 235, 期 -, 页码 606-613出版社
ELSEVIER
DOI: 10.1016/j.powtec.2012.11.022
关键词
Nanostructured mixture; Mechanical milling; Thermal explosion; Synthesis; Activation energy
The influence of the duration of preliminary mechanical activation on the microstructure of the powder mixture of 3Ti +Al and the features of the kinetics of the thermal explosion processes in milled powder mixtures were studied. It was shown that the formation of highly defective crystalline structures with high curvature of the lattice and high internal stress gradients took place with the increase of milling time. It was found that the features of heating during the thermal explosion process were determined by the features of the microstructure of the milled mixture. As a consequence, the composition of the product depended on the milling time and also on the heating rate of the mixture by the external heating source. Thus, the milling time and the heating rate can be considered as the control parameters in the research. The reacting system turned into the stable mode of phase formation characterized by the formation of mechanocomposites with the increase of milling time. The process was accompanied by the decrease in the effective activation energy of the synthesis down to the anomalous low value. The modes of the synthesis realization were determined to obtain a strictly single phase compound Ti3Al. It was hypothesized on the transition of the process from the diffusion regime of phase formation to the kinetic one with milling time. (C) 2012 Elsevier B.V. All rights reserved.
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