期刊
POLYMERS FOR ADVANCED TECHNOLOGIES
卷 22, 期 12, 页码 1555-1562出版社
WILEY-BLACKWELL
DOI: 10.1002/pat.1639
关键词
microspheres; monodisperse; precipitation polymerization; ethanol; solvent
资金
- Higher Educational Science and Technology Program of Shandong Province [JO8LCO3]
- Youth Science Foundation of Shandong Province [2007BS08027]
Precipitation polymerization of styrene (St) was carried out with pentaerythritol tetraacrylate (PETEA) to produce monodisperse crosslinked microspheres. A much safer ethanol replaced acetonitrile as a solvent in precipitation polymerization of monodisperse crosslinked poly(St-co-PETEA) microspheres. Monodisperse crosslinked microspheres with high monomer conversion were achieved within 4 hr. Uniform and well-separated monodisperse were obtained in ethanol when PETEA concentration varied from 30 vol% to 90 vol% and the particle diameter decreased from 0.75 to 0.58 mu m. The particle yield increased from 36.51 to 64.38% by increase in the initiator loading from 1 to 8 wt%. No coagulum occurred between particles when the polymerization time varied from 2 to 10 hr. Copyright (C) 2010 John Wiley & Sons, Ltd.
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