期刊
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
卷 52, 期 7, 页码 690-698出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/03602559.2012.762667
关键词
Crystallization; Poly(L-lactic acid); Poly(D-lactic acid); Stereocomplex; Structure
资金
- National Natural Science Foundation of China [51173041]
- Shanghai Leading Academic Discipline Project [B502]
- Shanghai Key Laboratory Project [08DZ2230500]
Effect of the addition of poly(D-lactic acid) (PDLA) as stereocomplex (SC) on crystallization behavior of poly(L-lactic acid) (PLLA) had been systemically investigated. The result indicated that the inclusion of PDLA with higher MW into PLLA exhibited lower t(1/2) and showed accelerated crystallization behavior. Meanwhile, SC formed in blends with higher MW of PDLA exhibited enhanced nucleation activity. In combination with both DSC and WAXD analysis, it was believed that nucleation process was more related to the crystalline size of SC. The result in this study would provide guidance for the application of SC as nucleating agent for the PLA-based products.
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