期刊
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
卷 48, 期 6, 页码 579-586出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/03602550902824408
关键词
Differential scanning calorimetry; Nanocomposite; Nonisothermal kinetics; Single-walled carbon nanotube
The nonisothermal melt crystallization kinetics of polypropylene (PP) and polypropylene/single-walled carbon nanotube (PP/SWNT) nanocomposite were analyzed according to Avrami and Mo models. The values of half-life, corrected composite rate constant and F(T) indicated that the crystallization rate increased with the increasing of cooling rates for PP and PP/SWNT. However, the crystallization rate of nanocomposite was found to be higher than that of PP at a certain cooling rate. Nucleation efficiency defined by Fillon et al. was obtained for PP/SWNT. In addition, the effective energy barrier for the nonisothermal melt crystallization process was calculated by using the Kissinger method.
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