Preparation and Properties of a Functional Polyacetylene with Quinoline-Based Heterocyclic Azo Pendants

A novel functional polyacetylene with D-pi-A conjugated quinoline-based heterocyclic azo pendants was designed and prepared to improve the polyacetylene properties. Its structure and properties were characterized and evaluated in details. The incorporation of D-pi-A conjugated quinoline-based heterocyclic azo pendants to the polyacetylene backbone increases the polymer solubility in polar solvents. Its UV-vis absorbance is sensitive to the presence of F- anions and results in UV-VIS spectrum red-shift by ca. 21 nm from 449 nm to 470 nm in dry DMSO.