期刊
POLYMER JOURNAL
卷 43, 期 4, 页码 364-369出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/pj.2011.2
关键词
addition reaction; charge transfer; electrochemistry; post-functionalization
资金
- MEXT, Japan
- Kato Foundation for Promotion of Science
- Grants-in-Aid for Scientific Research [22685023] Funding Source: KAKEN
A 7,7,8,8-tetracyanoquinodimethane polyester was converted into a strongly colored polyester with low-energy charge-transfer (CT) bands by treatment with electron-rich alkyne molecules under mild conditions. The post-functionalization was monitored by its ultraviolet-visible-near infrared (IR) spectra, which suggested a quantitative addition reaction without any side reactions. This result was further supported by H-1 and C-13 nuclear magnetic resonance, IR and elemental analyses. The functionalized polymer retained a high thermal stability with a decomposition onset temperature of similar to 200 degrees C and similar to 63% residual soot at 500 degrees C. The CT chromophores in the polymer showed a clear positive solvatochromism and redox behaviors in both anodic and cathodic directions. The HOMO and LUMO levels estimated from the first oxidation potential (E-ox,E- 1) and the first reduction potential (E-red,E- 1), respectively, were markedly elevated by this post-functionalization. The extent of HOMO elevation (1.45 eV) was more significant than that of LUMO elevation (0.44 eV). Polymer Journal (2011) 43, 364-369; doi:10.1038/pj.2011.2; published online 2 February 2011
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