期刊
POLYMER INTERNATIONAL
卷 63, 期 6, 页码 1011-1017出版社
WILEY
DOI: 10.1002/pi.4602
关键词
nanocomposite; graphene; electroactive; polyimide
资金
- Ministry of Education, Taiwan, R.O.C. [NSC 101-2113-M-033-005-MY1, 101-3113-P-002-026, 102-2622-E-007-016-CC1]
- Center-of-Excellence Program on Membrane Technology from the Ministry of Education, R.O.C.
- Department of Chemistry at Chung-Yuan Christian University (CYCU) [CYCU-01RD-RA002-11235]
- Center for Nanotechnology and Institute of Biomedical Technology at CYCU
Electroactive polyimide (EPI) nanocomposites with amino-capped aniline trimer and 4 '-(4,4 '-isopropylidene-diphenoxy)bis(phthalic anhydride) as monomers, and functionalized with carboxyl-graphene nanosheets, were prepared by thermal imidization. The as-prepared electroactive polyimide/graphene nanocomposite (EPGN) materials were then characterized by Fourier transform infrared spectroscopy and transmission electron microscopy. In situ monitoring of the redox behavior of the as-prepared EPGN materials was performed by cyclic voltammetry studies. The effects of material composition on the mechanical, thermal, thermal transport, dielectric and molecular barrier properties of EPGN membranes were investigated by dynamic mechanical analysis, TGA, DSC, the transient plane source technique, LCR meter and gas permeability analyzer, respectively. It should be noted that all the properties of the EPGN membranes were found to improve substantially over those of non-electroactive polyimide and EPI. For example, upon loading of 1 wt% graphene, EPGN membranes were found to have an increase of over 20%, 5%, 65% and 20% in mechanical strength, thermal stability, thermal conductivity and dielectric constant, respectively, and a reduction of over 20% in gas permeability. (c) 2013 Society of Chemical Industry
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