期刊
POLYMER INTERNATIONAL
卷 61, 期 1, 页码 111-117出版社
WILEY-BLACKWELL
DOI: 10.1002/pi.3154
关键词
solvent-resistant nanofiltration; two-step method; polyimide; heat imidization
资金
- Ministry of Education of China [308003]
- National Natural Science Foundation of China [20804002]
- Specialized Research Fund for the Doctoral Program of Higher Education [20070010018]
This study investigated the preparation of polyimide solvent-resistant nanofiltration membranes by a two-step method (casting the membrane first and then crosslinking by the thermal imidization method). The influences of polymer concentration, thickness of membranes, temperature of the imidization, phase inversion time and thermal imidization procedure were studied. The membranes with the highest rejection rate of Fast Green FCF (molecular weight 808.86 g mol-1) were prepared in the following conditions: polymer concentration 13 wt%, phase inversion time 1 h, membrane thickness 150 mu m and thermal imidization procedure 200 degrees C for 2.5 h, 250 degrees C for 2 h and 300 degrees C for 2 h in a vacuum environment; the heating rate was 5 degrees C min-1. The membrane was stable in most of the solvents tested and the fluxes of some common solvents were equal to or higher than a number of commercial solvent-resistant nanofiltration membranes. A much higher rejection of dyes in water than in methanol was observed in the filtration experiments and a new way to explain it was developed. Copyright (C) 2011 Society of Chemical Industry
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