期刊
POLYMER DEGRADATION AND STABILITY
卷 98, 期 5, 页码 1081-1088出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2013.01.008
关键词
Polyethylene; Methyl esters of unsaturated fatty acids; Co-oxidation; Kinetic modeling; Chemiluminescence
资金
- competitivity pole MOV'EO
The thermal oxidation of polyethylene (PE) impregnated by the methyl esters of unsaturated fatty acids (UFEs) was studied using chemiluminescence, and infra-red spectrophotometry. It was shown that the presence of UFEs accelerates the PE aging process. This can be interpreted as a co-oxidation phenomenon. In this study, the previously established models for PE and UFEs self-oxidation have been coupled in order to develop a co-oxidation model. Using the existing rate constants for the PE and UFEs self-oxidations, this model can simulate the complex shape of the kinetic curves of PE-UFE co-oxidation. (C) 2013 Elsevier Ltd. All rights reserved.
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