期刊
POLYMER DEGRADATION AND STABILITY
卷 97, 期 6, 页码 987-994出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2012.03.010
关键词
Polyimides; Bis-benzimidazole; Synthesis; Thermal stability; Mechanical property
资金
- NSFC [50873021, 51173024]
- Shuguang Plan [09SG30]
- Shanghai Leading Academic Discipline Project [B603]
- 111 Project [111-2-04]
A new aromatic heterocyclic diamine monomer containing bis-benzimidazole rings, 2,2'-p-phenylene-bis(5-aminobenzimidazole) (PBABI), was synthesized from 2,2'-p-phenylene-bis (5-nitrobenzimidazole) with high yield via the reaction between 4-nitro-1,2-phenylenediamine and terephthalyl chloride. The composition and structure of the resulting diamine monomer were studied by means of FTIR, H-1 and C-13 NMR and elemental analysis. A series of polyimides holding bis-benzimidazole rings in main chain were produced by reacting PBABI with the aromatic dianhydrides 3,3',4,4'-biphenyl tetracarboxylic dianhydride, 4,4'-oxydiphthalic anhydride, benzophenone tetracarboxylic dianhydride and pyromellitic dianhydride via a conventional, two-step procedure. X-ray diffraction and differential scanning calorimetry were employed to investigate the polyimides, revealing them essentially amorphous. The polyimides possess thermal stabilities of up to 560 degrees C for a 5% weight loss and glass transition temperatures above 450 degrees C. In addition, these high performance polymers have excellent mechanical properties, exhibiting tensile strengths of 120-180 MPa and tensile moduli of 4.83-5.79 GPa without any stretching. The rigid-rod structure of polyimides and the hydrogen bonding of their inter-macromolecular chains are most likely responsible for the outstanding properties of the polyimides. (C) 2012 Elsevier Ltd. All rights reserved.
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