期刊
POLYMER DEGRADATION AND STABILITY
卷 96, 期 3, 页码 342-349出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2010.02.023
关键词
Flame retardance; Styrenic; Phosphorus; Phosphate; Phosphonate
Organohalogen compounds, principally brominated aromatics, continue to be the largest selling flame retardants worldwide. However, there is increasing concern about the bioaccumulation and potential toxicity of these compounds. Consequently, there is great interest in the development of effective alternatives to these materials. Organophosphorus compounds seem to offer the most promise as replacements for halogen-containing flame retardants. One approach to flame-retarding vinyl polymers is to develop reactive monomers containing high levels of phosphorus which may be incorporated directly into the polymer structure. Five phosphorus monomers for use in making fire-retardant copolymers with styrene have been synthesized. A comparative study of the thermal stability of the copolymers has been conducted. Preliminary potential fire behavior data have been obtained using pyrolysis combustion flow calorimetry. (c) 2010 Elsevier Ltd. All rights reserved.
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