The influence of UV irradiation on the properties of chitosan films containing keratin

The mechanical, thermal and surface properties of chitosan and chitosan containing keratin hydrolysates have been studied and the influence of UV irradiation on these properties has been compared. The surface properties of chitosan films containing 5%, 15% and 30% of keratin hydrolysate before and after UV irradiation (lambda = 254 nm) were investigated by means of contact angle measurements allowing the calculation of surface free energy. The chemical and structural changes during UV irradiation were studied by UV vis and FTIR-ATR spectroscopy. The changes in mechanical properties such as breaking strength, percentage elongation and Young's modulus have been investigated. The results have shown that the mechanical properties of the chitosan/keratin films were greatly affected by UV irradiation, but the level of the changes of these properties was smaller in the blend than in pure chitosan and strongly dependent on the time of irradiation and composition of the samples. The contact angle and the surface free energy were altered by UV irradiation, which indicates photooxidation and an increase of polarity of specimens. The range of these changes point to greater susceptibility of chitosan to photooxidation in the presence of keratin. (C) 2010 Elsevier Ltd. All rights reserved.