期刊
POLYMER COMPOSITES
卷 33, 期 5, 页码 838-842出版社
WILEY-BLACKWELL
DOI: 10.1002/pc.22220
关键词
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资金
- National Natural Science Foundation of China [50873094]
- Major Project in Public Interest of Henan Province [HNZB [2011] N91]
- SRF for ROCS, State Education Ministry
Novel biodegradable poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [P(3HB-co-4HB)]/organoclay nanocomposites were prepared via solution casting. Exfoliated nanocomposite structure was confirmed by wide-angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) for the nanocomposites with low organoclay loadings (=3 wt%), whereas the mixtures of exfoliated and unexfoliated organoclays were appeared in the nanocomposite with an organoclay content of 5 wt%. The organoclay fillers accelerated significantly the cold crystallization process of P(3HB-co-4HB) matrix. The thermal stability of the nanocomposites was in general better than that of pristine P(3HB-co-4HB). Considerable increase in tensile modulus was observed for the nanocomposites, especially at an organoclay content of 3 wt%. These results demonstrated that the nanocomposites improved the material properties of P(3HB-co-4HB). POLYM. COMPOS., 2012. (c) 2012 Society of Plastics Engineers
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