期刊
POLYMER CHEMISTRY
卷 5, 期 18, 页码 5236-5246出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py00496e
关键词
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资金
- CSIRO-CMSE
Recently developed sequential reversible addition-fragmentation chain transfer (RAFT) polymerization protocols allow the rapid, fully unattended preparation of quasi-block copolymer libraries that cover a wide range of copolymer compositions in an automated synthesizer. This contribution explores the scope and limitations of this sequential approach for the synthesis of higher order quasi-multiblock copolymers (including copolymer sequences of BAB, CBABC, ABC and ABCD). These syntheses illustrate the utility of this high-throughput approach for the one pot synthesis of functional polymers of increased complexity. Additionally, the use of this experimental technique for method development is highlighted.
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