期刊
POLYMER CHEMISTRY
卷 5, 期 6, 页码 1857-1862出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py01486j
关键词
-
资金
- National Science Foundation of China [21104039]
A multicomponent reaction (MCR) has been carried out on the platform of controlled radical polymerization (CRP) to construct a 'one pot' MCR-CRP system for the facile preparation of well-defined functional polymers. In the current work, a novel 'one pot' system has been built through a combination of the Kabachnik-Fields (KF) reaction and reversible addition fragmentation chain transfer (RAFT) polymerization. Compared to a traditional stepwise method and polymer post-polymerization modification, this novel 'one pot' system exhibited distinct advantages to much more facilely and efficiently prepared well-defined poly(aminophosphonate)s (polyAPPs). A series of unique polyAPPs have also been successfully prepared through this KF-RAFT system, suggesting this novel method is a general and versatile approach to prepare well-defined organophosphorous polymers.
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