期刊
POLYMER CHEMISTRY
卷 5, 期 17, 页码 5109-5115出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py00595c
关键词
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资金
- National Natural Science Foundation of China [21374093]
- Loker Hydrocarbon Research Institute
Polyfluorenes and their nanoparticles are of interest because of their desirable photoluminescent properties. Here, we report the synthesis of a polyfluorene macromonomer p-[poly(9,9-dihexylfluorene-2,7-diyl] styrene (PFS) and their narrow polydispersity PFS-containing random copolymers with t-butyl acrylate [P(PFS-r-t-BA)s], i.e. via both reversible addition-fragmentation chain transfer (RAFT) and atom transfer radical polymerization (ATRP). The acid hydrolysis of P(PFS-r-t-BA) gives the corresponding amphiphilic P(PFS-r-acrylic acid) [P(PFS-r-AA)] polyelectrolytes, which self-assemble into photoluminescent nanoparticles in aqueous solutions. The P(PFS-r-AA) was shown to act as a scaffold for the incorporation of other pigments, which allowed tunable emissions via varying pigment combinations by Forster resonance energy transfer. The occurrence of strong white light emission was demonstrated.
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