期刊
POLYMER CHEMISTRY
卷 4, 期 17, 页码 4566-4569出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00798g
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资金
- NSF [CHE-1110967, DMR-1205302]
- Robert A. Welch Foundation [AH-0033]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1110967] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1205302] Funding Source: National Science Foundation
A new microporous imine-linked porous porphyrin polymer, CuPor-BPDC, has been solvothermally synthesized. The CuPor-BPDC showed high CO2 capture (5.5 wt% at 273 K/1 bar) and very good selectivity for CO2/CH4 adsorption (5.6) at 1.0 bar and 273 K, and exhibited a BET surface area of 442 m(2) g(-1) with high thermal stability (up to 400 degrees C), thus showing good potential for CO2 capture.
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